proton abstraction造句
例句與造句
- In alkene radicals proton abstraction to an alkyne is preferred.
- In the Birch reduction, the secondary reaction is proton abstraction from an alcohol.
- To be specific, it is involved in the cofactor-assisted proton abstraction from the substrate molecule.
- In the negative mode, however, the ions are produced by either proton abstraction or adduct formation.
- It acts as a nucleophile, facilitates proton abstraction, and is also the leaving group in the final step.
- It's difficult to find proton abstraction in a sentence. 用proton abstraction造句挺難的
- The aldimine undergoes proton abstraction at the ?-carbon followed by elimination to generate an amino-acrylate intermediate.
- The resulting enolate attacks CO 2 to form malonyl CoA . In a competing mechanism, proton abstraction is concerted with the attack of acetyl CoA.
- The carbanion forms by proton abstraction of the acidic ?-proton by pyridine ( now serving a double role ) akin to the Knoevenagel condensation.
- Enzymes alter the electronic structure by protonation, proton abstraction, electron transfer, geometric distortion, hydrophobic partitioning, and interaction with Lewis acids and bases.
- Interestingly, regardless of the solvents the KIE were found to be greater than 2, indicating the relevance of proton abstraction in the rate-determining step.
- Combustion of hydrocarbons is thought to be initiated by hydrogen atom abstraction ( not proton abstraction ) from the fuel to oxygen, to give a hydroperoxide radical ( HOO ).
- Recent mutagenic studies of ASL homologues have shown that Histidine 162 or Threonine 161 of ASL is responsible for the proton abstraction of the C?, either directly or indirectly through a water molecule.
- In the first step an azido compound is formed in situ in a nucleophilic attack of a second azide ion on this alkene with more double bond rearrangements and proton abstraction from a proton source.
- The Bronsted acid remains hydrogen-bonded to the resulting enolate in the enolate-addition step to the aldehyde, and finally ensures efficient proton transfer in the rate-determining proton abstraction step.
- Sulfur tetrazole radical derived from photolysis of disulfide and carbon radical derived from photolysis of t-butyl peroxide followed by proton abstraction from triethylamineWhen reactivity-selectivity relationships do exist they signify different reaction modes.
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